Group of Chemicals : Glycerine
Commercial Name : Crude/Refined Glycerine
Physical & Chemical Properties
Boiling point, deg C at 760mm Hg
290
Melting point, deg C
18
Flash point, deg C
160
Auto-ignition temperature, deg C
400
Density, g/ml t 20 deg C
1.263
Relative vapor density (air=1)
3.2
Relative density at 20 deg C of saturated mixture vapor/ir (air=1) 1.0
Vapor pressure, mm Hg at 50 deg C
0.0023
Solubility in water, g/100 ml at 50 deg C
Infinite
Electrical conductivity, pS/m
6.4×105
Relative molecular mass
92.1
Log P octanol/water
-2.6
Chemical Name
: 1, 2, 3 - propanetriot
Gross Formula
: C3H3O3
Important Characteristics
• Colourless to brownish hygroscopic
viscous liquid, Fatty odor when crude
Odourless when
refined
• Vapour mixes readily with
air. Able to polymerise above 149 deg C.
Decomposes when heated above
290 deg C, giving off corrosive gas.
• Reacts voilently with strong
oxidants, with risk of fire and explosion
• Crude glycerine may be corrosive.
Refined glycerine not corrosive.
Irritating to eyes
and skin
• Low toxicity and not considered
hazardous to human beings.
Hazards/Prevention/First-Aid Fire
• Combustible
• Keep away from open flame,
no smoking
• Use dry powder, foam, carbon
tetrachloride, carbon dioxide for
extinguishing
Inhalation
• Sore throat, cough
• Use self-contained breathing
equipment if in confined space
• Ventilation
• Remove to fresh air. If suffocation
is serious take to a doctor
Skin
• Redness
• Use gloves
• Absorb water from skin/body
if contacted for too long
• Remove containated clothing,
wash skin with water and soap
Eyes
• Redness, pain
• Use face shield
• Flush with water, take to
a doctor if necessary
Ingestion
• Diarrhoea, headache, nausea
• Rinse mouth, drink plenty
of water to induce vormitting, take to a doctor
Spillage
• Collect leakage in sealable
containers, soak up with sand or other inert
absorbent and remove
to safe place.
Flush away remainer
with water
Handling And Storage
• Use gloves and wear goggles
when handling
• Keep in a cool and place,
avoid extrem heat and cold
• Avoid direct fire, oxidising
agents
• In bulk, store above melting
point, Temperature higher than necessary
degrades quality
at rate dependent
on time and temperature
of exposure
• Exposure to ultraviolet light,
especially sunlight must be miniised to
prevent quality
loss
Notes
• Product readily biodegradable
• Do not solidify until well
below melting point
• Always work safely around
open hathces on bulk tanks